Investigation of the chemical conversions of diols and organic mixtures - Communication 18. Investigation of the thermal decomposition of 3-monoalkyl-substituted β-oxides, using the microreactor technique

M. Bartok, B. Kozma, N. I. Shuikin

Research output: Contribution to journalArticle

Abstract

1. The thermal conversions of 3-monoalkyl-substituted β-oxides were investigated, using a microreactor mounted in a chromatograph. 2. In the thermal decomposition of this type of β-oxides, there are two primary processes. The main direction of the reaction is decomposition of the molecules to formaldehyde and the corresponding olefins (∼90%). In addition to decomposition, isomerization of the β-oxides and aldehydes (5-7%) was also observed; the formation of the latter may be explained by the influence of the walls of the microreactor. 3. Secondary processes may include decarbonylation of the primary products.

Original languageEnglish
Pages (from-to)123-126
Number of pages4
JournalBulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume17
Issue number1
DOIs
Publication statusPublished - Jan 1 1968

ASJC Scopus subject areas

  • Chemistry(all)

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