Investigation of a long-lived intermediate in the photo-oxidation of chlorocuprate(I) complexes

O. Horváth, Sándor Papp

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Abstract

The decay of a long-lived intermediate formed in the photo-oxidation of acidic solutions of chlorocuprate(I) complexes was examined. The dependences of the decay rate on the components of this system (CuI, CuII, Cl- andH+) confirmed assumptions that dimeric or polymeric CuI-CuII chloro complexes are formed during the photo-oxidation. The quantum yield obtained indirectly as well as the estimate for the concentration of the intermediate were in accordance with results from previous experiments.

Original languageEnglish
Pages (from-to)211-222
Number of pages12
JournalJournal of Photochemistry
Volume31
Issue number2-3
DOIs
Publication statusPublished - 1985

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Photooxidation
Quantum yield
Experiments

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Investigation of a long-lived intermediate in the photo-oxidation of chlorocuprate(I) complexes. / Horváth, O.; Papp, Sándor.

In: Journal of Photochemistry, Vol. 31, No. 2-3, 1985, p. 211-222.

Research output: Contribution to journalArticle

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