Investigation of a long-lived intermediate in the photo-oxidation of chlorocuprate(I) complexes

Ottó Horváth, Sándor Papp

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Abstract

The decay of a long-lived intermediate formed in the photo-oxidation of acidic solutions of chlorocuprate(I) complexes was examined. The dependences of the decay rate on the components of this system (CuI, CuII, Cl- andH+) confirmed assumptions that dimeric or polymeric CuI-CuII chloro complexes are formed during the photo-oxidation. The quantum yield obtained indirectly as well as the estimate for the concentration of the intermediate were in accordance with results from previous experiments.

Original languageEnglish
Pages (from-to)211-222
Number of pages12
JournalJournal of Photochemistry
Volume31
Issue number2-3
DOIs
Publication statusPublished - Dec 1985

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