The reassignment of the CH stretching vibration fundamentals of cyclohexane is made by combination of experimental-i.r. and Raman spectroscopy-and theoretical-ab initio calculation-methods. The Raman active bands are determined experimentally by polarized measurements. The position and intensity of the i.r. active bands are obtained by deconvolution of the band envelopes of the vapour phase spectrum. The calculated frequencies and relative intensities are in very good agreement with the experimental values, thus confirming the feasibility of the reassignment.
|Number of pages||4|
|Journal||Spectrochimica Acta Part A: Molecular Spectroscopy|
|Publication status||Published - 1990|
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