Interpretation of isotope effects on the solubility of gases

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Abstract

Experimental results concerning the isotope effect on the solubility of gases are reviewed and the theory of the isotope effect on Henry's law constants is derived in terms of the statistical mechanical theory of condensed phase isotope effects. The performance of the method is demonstrated by detailed analysis of some of the available experimental data on solubility isotope effect.

Original languageEnglish
Pages (from-to)S53-S57
JournalNukleonika
Volume47
Issue numberSUPPL.1
Publication statusPublished - Dec 1 2002

Keywords

  • Gas solubility
  • Henry's law constant
  • Isotope effect
  • Isotopic fractionation
  • Partition function

ASJC Scopus subject areas

  • Nuclear and High Energy Physics
  • Nuclear Energy and Engineering
  • Instrumentation
  • Safety, Risk, Reliability and Quality
  • Condensed Matter Physics
  • Waste Management and Disposal

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