Interaction of nonylphenyl and tributylphenyl ethylene oxide ionic surfactants with highly soluble cyclodextrin derivatives

T. Cserháti, Eva Fenyvesi, Jozsef Slejtli

Research output: Contribution to journalArticle

23 Citations (Scopus)

Abstract

The modification of the hydrophobicity of some ethoxylated nonylphenol and tributylphenol surfactants with various soluble β-cyclodextrin polymers has been studied by reversed-phase chromatography. Stepwise regression analysis proved that the complex forming capacity of surfactants decreases with increasing diameter of the hydrophobic moiety of surfactants, the properties of the crosslinking agent used for preparation of the polymers has no significant effect on the host-guest interaction, the presence of carboxyl groups in the polymer considerably improved the complex stability.

Original languageEnglish
Pages (from-to)181-188
Number of pages8
JournalJournal of Inclusion Phenomena and Molecular Recognition in Chemistry
Volume14
Issue number2
DOIs
Publication statusPublished - Jun 1992

Fingerprint

ethylene oxide
Ethylene Oxide
cyclodextrins
Cyclodextrins
Surface-Active Agents
surfactants
polymers
chemical derivatives
Polymers
carboxyl group
interactions
Reverse-Phase Chromatography
crosslinking
chromatography
Hydrophobicity
hydrophobicity
Chromatography
Hydrophobic and Hydrophilic Interactions
Regression analysis
Crosslinking

Keywords

  • alkylphenol ethylene oxide surfactants
  • reversed-phase thin-layer chromatography
  • Water soluble cyclodextrin polymer

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Chemistry(all)

Cite this

@article{8e68bb5e3939484e9e0309b7cf39dbed,
title = "Interaction of nonylphenyl and tributylphenyl ethylene oxide ionic surfactants with highly soluble cyclodextrin derivatives",
abstract = "The modification of the hydrophobicity of some ethoxylated nonylphenol and tributylphenol surfactants with various soluble β-cyclodextrin polymers has been studied by reversed-phase chromatography. Stepwise regression analysis proved that the complex forming capacity of surfactants decreases with increasing diameter of the hydrophobic moiety of surfactants, the properties of the crosslinking agent used for preparation of the polymers has no significant effect on the host-guest interaction, the presence of carboxyl groups in the polymer considerably improved the complex stability.",
keywords = "alkylphenol ethylene oxide surfactants, reversed-phase thin-layer chromatography, Water soluble cyclodextrin polymer",
author = "T. Cserh{\'a}ti and Eva Fenyvesi and Jozsef Slejtli",
year = "1992",
month = "6",
doi = "10.1007/BF01029666",
language = "English",
volume = "14",
pages = "181--188",
journal = "Journal of Inclusion Phenomena and Macrocyclic Chemistry",
issn = "0923-0750",
publisher = "Kluwer Academic Publishers",
number = "2",

}

TY - JOUR

T1 - Interaction of nonylphenyl and tributylphenyl ethylene oxide ionic surfactants with highly soluble cyclodextrin derivatives

AU - Cserháti, T.

AU - Fenyvesi, Eva

AU - Slejtli, Jozsef

PY - 1992/6

Y1 - 1992/6

N2 - The modification of the hydrophobicity of some ethoxylated nonylphenol and tributylphenol surfactants with various soluble β-cyclodextrin polymers has been studied by reversed-phase chromatography. Stepwise regression analysis proved that the complex forming capacity of surfactants decreases with increasing diameter of the hydrophobic moiety of surfactants, the properties of the crosslinking agent used for preparation of the polymers has no significant effect on the host-guest interaction, the presence of carboxyl groups in the polymer considerably improved the complex stability.

AB - The modification of the hydrophobicity of some ethoxylated nonylphenol and tributylphenol surfactants with various soluble β-cyclodextrin polymers has been studied by reversed-phase chromatography. Stepwise regression analysis proved that the complex forming capacity of surfactants decreases with increasing diameter of the hydrophobic moiety of surfactants, the properties of the crosslinking agent used for preparation of the polymers has no significant effect on the host-guest interaction, the presence of carboxyl groups in the polymer considerably improved the complex stability.

KW - alkylphenol ethylene oxide surfactants

KW - reversed-phase thin-layer chromatography

KW - Water soluble cyclodextrin polymer

UR - http://www.scopus.com/inward/record.url?scp=34249842273&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=34249842273&partnerID=8YFLogxK

U2 - 10.1007/BF01029666

DO - 10.1007/BF01029666

M3 - Article

AN - SCOPUS:34249842273

VL - 14

SP - 181

EP - 188

JO - Journal of Inclusion Phenomena and Macrocyclic Chemistry

JF - Journal of Inclusion Phenomena and Macrocyclic Chemistry

SN - 0923-0750

IS - 2

ER -