Interaction between electrodeposited bismuth and palladium substrate

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Abstract

Bismuth deposition onto polycrystalline Pd surfaces has been studied in 0.5 M H2SO4, 1 M HClO4 and 1 M HCl supporting electrolyte and it has been shown that a spontaneous interaction (probably alloy formation) takes place between Bi deposit and Pd substrate. The Bi/Pd atomic ratio could be increased up to about 0.6. Irreversible Bi adsorption on Pd substrate has been demonstrated.

Original languageEnglish
Pages (from-to)83-92
Number of pages10
JournalACH - Models in Chemistry
Volume133
Issue number1-2
Publication statusPublished - Dec 1 1996

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ASJC Scopus subject areas

  • Chemistry(all)

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