Infrared spectra of tetrahydrophyrido[1,2-a]pyrimidin-4-one derivatives

G. Horváth, I. Hermecz, L. Pusztay, A. I. Kiss

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

During the infrared spectrometric investigation of a considerable number of 1,3-dicarbonyltetrahydropyridopyrimidine derivatives, frequency coupling of v(C=O), O-cis, O-trans conformations and polymorphism were observed. It is generally accepted that the magnitude of the frequency coupling is characterized by the band shifts and by the intensity difference of the coupled vibrational bands. However, for the tetrahydropyridopyrimidine derivatives studied here only the intensity difference of the coupled bands is characteristic of the extent of the coupling of vibrations. The frequency difference of the coupled bands depends primarily on the chemical environment.

Original languageEnglish
Pages (from-to)371-373
Number of pages3
JournalAnalyst
Volume117
Issue number3
DOIs
Publication statusPublished - Jan 1 1992

Keywords

  • Conformation
  • Frequency coupling
  • Infrared
  • Polymorphism
  • Pyridopyrimidine

ASJC Scopus subject areas

  • Analytical Chemistry
  • Biochemistry
  • Environmental Chemistry
  • Spectroscopy
  • Electrochemistry

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