Infrared, raman and force field studies of ethylmercury(II) halides

J. Mink, P. L. Goggin

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

Vibrational assignments for Hg(C2H5)X (X Cl, Br or I) and HgBr(C2D5) are proposed, on the basis of solution studies as far as possible. For the bromides, 21 force constants are refined in the presence of 12 constrained values from C2H5Cl and 12 of these are used as additional constraints in refining 9 force constants for the chloride and iodide. The nature of the normal modes of Hg(C2H5)C1 is discussed. The Hg-C stretching force constants of the ethyl compounds is marginally higher than in corresponding methyl derivatives.

Original languageEnglish
Pages (from-to)129-146
Number of pages18
JournalJournal of Organometallic Chemistry
Volume185
Issue number1
DOIs
Publication statusPublished - 1980

Fingerprint

Iodides
Bromides
field theory (physics)
Refining
Stretching
halides
Chlorides
Infrared radiation
Derivatives
ethyl compounds
refining
iodides
bromides
chlorides

ASJC Scopus subject areas

  • Biochemistry
  • Chemical Engineering (miscellaneous)
  • Inorganic Chemistry
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Science (miscellaneous)
  • Materials Chemistry

Cite this

Infrared, raman and force field studies of ethylmercury(II) halides. / Mink, J.; Goggin, P. L.

In: Journal of Organometallic Chemistry, Vol. 185, No. 1, 1980, p. 129-146.

Research output: Contribution to journalArticle

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