Indole-2-carboxylate-and dihydroindole-2-carboxylate-CaFe layered double hydroxide nanocomposites-synthesis, characterisation and the effect of synthesis variables

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Potential organocatalysts, N-containing fully or partially unsaturated heterocyclic anions, indole-2-carboxylate and dihydroindole-2-carboxylate) were immobilised in CaFe layered double hydroxide with the dehydration-rehydration method from aqueous ethanol and acetone. The structure of the resulting organic-inorganic hybrids was characterised by various instrumental methods (powder X-ray diffraction, scanning electron microscopy, energy dispersive X-ray fluorescence with elemental mapping, thermogravimetry) and molecular modelling. It was found that the solvent mixture used for the synthesis exerted tremendous difference in the interlayer spacings of the obtained inorganic-organic hybrids.

Original languageEnglish
Title of host publicationECCM 2012 - Composites at Venice, Proceedings of the 15th European Conference on Composite Materials
PublisherEuropean Conference on Composite Materials, ECCM
ISBN (Print)9788888785332
Publication statusPublished - 2012
Event15th European Conference on Composite Materials: Composites at Venice, ECCM 2012 - Venice, Italy
Duration: Jun 24 2012Jun 28 2012

Other

Other15th European Conference on Composite Materials: Composites at Venice, ECCM 2012
CountryItaly
CityVenice
Period6/24/126/28/12

Fingerprint

Molecular modeling
Acetone
Dehydration
X ray powder diffraction
Anions
Thermogravimetric analysis
Nanocomposites
Ethanol
Negative ions
Fluorescence
X rays
Scanning electron microscopy
hydroxide ion
indole-2-carboxylate

Keywords

  • CaFe layered double hydroxide host
  • Effects of synthesis variables
  • Indole carboxylate derivative guests
  • Instrumental characterisation

ASJC Scopus subject areas

  • Ceramics and Composites

Cite this

Sipiczki, M., Kukovecz, Á., Kónya, Z., Sipos, P., & Pálinkó, I. (2012). Indole-2-carboxylate-and dihydroindole-2-carboxylate-CaFe layered double hydroxide nanocomposites-synthesis, characterisation and the effect of synthesis variables. In ECCM 2012 - Composites at Venice, Proceedings of the 15th European Conference on Composite Materials European Conference on Composite Materials, ECCM.

Indole-2-carboxylate-and dihydroindole-2-carboxylate-CaFe layered double hydroxide nanocomposites-synthesis, characterisation and the effect of synthesis variables. / Sipiczki, M.; Kukovecz, Á; Kónya, Z.; Sipos, P.; Pálinkó, I.

ECCM 2012 - Composites at Venice, Proceedings of the 15th European Conference on Composite Materials. European Conference on Composite Materials, ECCM, 2012.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Sipiczki, M, Kukovecz, Á, Kónya, Z, Sipos, P & Pálinkó, I 2012, Indole-2-carboxylate-and dihydroindole-2-carboxylate-CaFe layered double hydroxide nanocomposites-synthesis, characterisation and the effect of synthesis variables. in ECCM 2012 - Composites at Venice, Proceedings of the 15th European Conference on Composite Materials. European Conference on Composite Materials, ECCM, 15th European Conference on Composite Materials: Composites at Venice, ECCM 2012, Venice, Italy, 6/24/12.
Sipiczki M, Kukovecz Á, Kónya Z, Sipos P, Pálinkó I. Indole-2-carboxylate-and dihydroindole-2-carboxylate-CaFe layered double hydroxide nanocomposites-synthesis, characterisation and the effect of synthesis variables. In ECCM 2012 - Composites at Venice, Proceedings of the 15th European Conference on Composite Materials. European Conference on Composite Materials, ECCM. 2012
Sipiczki, M. ; Kukovecz, Á ; Kónya, Z. ; Sipos, P. ; Pálinkó, I. / Indole-2-carboxylate-and dihydroindole-2-carboxylate-CaFe layered double hydroxide nanocomposites-synthesis, characterisation and the effect of synthesis variables. ECCM 2012 - Composites at Venice, Proceedings of the 15th European Conference on Composite Materials. European Conference on Composite Materials, ECCM, 2012.
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