In situ Mössbauer study of framework substituted (Fe)ZSM-5 zeolites

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Abstract

The coordination states, stability, and reducibility of isomorphically substituted framework Fe(III) were studied in ZSM-5 zeolites (Si/Fe = 22) by in situ Mössbauer spectroscopy. Supplementary methods as X-ray diffraction and temperature-programmed reduction were used as well, and the catalytic activity of (Fe)ZSM-5 was tested in CO hydrogenation. The effects of exchange of charge neutralizing protons for Li+ were also studied. The measurements revealed that the symmetry of coordination of the framework Fe(III) depends considerably on the nature of charge compensation. It can be suggested that Brönsted acidic bridged hydrogen induces greater asymmetry around the framework Fe(III) than that generated by cationic (e.g., Li+ H3O+, or PrNH3+) compensation. The framework Fe(III) withstands hydrogen reduction and CO + H2 treatment at 570 K, but a part of these substituted ions can be reduced to Fe2+ state at 670 K. Li+ ion exchange decreases the reducibility of the framework Fe(III).

Original languageEnglish
Pages (from-to)214-222
Number of pages9
JournalZeolites
Volume11
Issue number3
DOIs
Publication statusPublished - 1991

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hydrogen
symmetry
asymmetry
ion exchange
spectroscopy
X-ray diffraction
ion
temperature
in situ
co-ordination
effect
method

Keywords

  • Ferrisilicate
  • framework Fe (III)
  • iron coordination
  • Mössbauer spectroscopy

ASJC Scopus subject areas

  • Environmental Science(all)

Cite this

In situ Mössbauer study of framework substituted (Fe)ZSM-5 zeolites. / Lázár, K.; Páł, Borbély G.; Beyer, H.

In: Zeolites, Vol. 11, No. 3, 1991, p. 214-222.

Research output: Contribution to journalArticle

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AU - Páł, Borbély G.

AU - Beyer, H.

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N2 - The coordination states, stability, and reducibility of isomorphically substituted framework Fe(III) were studied in ZSM-5 zeolites (Si/Fe = 22) by in situ Mössbauer spectroscopy. Supplementary methods as X-ray diffraction and temperature-programmed reduction were used as well, and the catalytic activity of (Fe)ZSM-5 was tested in CO hydrogenation. The effects of exchange of charge neutralizing protons for Li+ were also studied. The measurements revealed that the symmetry of coordination of the framework Fe(III) depends considerably on the nature of charge compensation. It can be suggested that Brönsted acidic bridged hydrogen induces greater asymmetry around the framework Fe(III) than that generated by cationic (e.g., Li+ H3O+, or PrNH3+) compensation. The framework Fe(III) withstands hydrogen reduction and CO + H2 treatment at 570 K, but a part of these substituted ions can be reduced to Fe2+ state at 670 K. Li+ ion exchange decreases the reducibility of the framework Fe(III).

AB - The coordination states, stability, and reducibility of isomorphically substituted framework Fe(III) were studied in ZSM-5 zeolites (Si/Fe = 22) by in situ Mössbauer spectroscopy. Supplementary methods as X-ray diffraction and temperature-programmed reduction were used as well, and the catalytic activity of (Fe)ZSM-5 was tested in CO hydrogenation. The effects of exchange of charge neutralizing protons for Li+ were also studied. The measurements revealed that the symmetry of coordination of the framework Fe(III) depends considerably on the nature of charge compensation. It can be suggested that Brönsted acidic bridged hydrogen induces greater asymmetry around the framework Fe(III) than that generated by cationic (e.g., Li+ H3O+, or PrNH3+) compensation. The framework Fe(III) withstands hydrogen reduction and CO + H2 treatment at 570 K, but a part of these substituted ions can be reduced to Fe2+ state at 670 K. Li+ ion exchange decreases the reducibility of the framework Fe(III).

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