In situ DRIFT study of nonoxidative methane reaction on Mo/SnO2 catalyst

Heider Nasser, A. Rédey, Tatiana Yuzhakova, József Kovács

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The Mo/SnO2 catalyst was prepared by the impregnation method and characterized by thermal analysis, X-ray diffractometry, diffuse reflectance infrared (DRIFT) spectroscopy as well as N2 adsorption/desorption (BET method) techniques. The results permit to infer that the highly dispersed Mo ions strongly affect SnO2 crystallization forming only MoO 3 and SnO2 phases. Moreover, the thermal behavior of Mo/SnO2 showed the dissolution of MoO3 in SnO2 crystals at temperatures above 750°C. Nevertheless, reduced MoO 3/SnO2 presented marked activity and selectivity towards CH4 decomposition at 700°C so as to forming a formaldehyde intermediate but rather favored the formation of CO2.

Original languageEnglish
Pages (from-to)165-173
Number of pages9
JournalReaction Kinetics and Catalysis Letters
Volume94
Issue number1
DOIs
Publication statusPublished - Jun 2008

Fingerprint

Methane
formaldehyde
dissolving
thermal analysis
methane
selectivity
desorption
infrared spectroscopy
crystallization
reflectance
decomposition
catalysts
Catalysts
adsorption
Crystallization
Formaldehyde
Impregnation
X ray diffraction analysis
Thermoanalysis
crystals

Keywords

  • DRIFT
  • Methane
  • Molybdena-tin
  • TG-DTA
  • XRD

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Catalysis

Cite this

In situ DRIFT study of nonoxidative methane reaction on Mo/SnO2 catalyst. / Nasser, Heider; Rédey, A.; Yuzhakova, Tatiana; Kovács, József.

In: Reaction Kinetics and Catalysis Letters, Vol. 94, No. 1, 06.2008, p. 165-173.

Research output: Contribution to journalArticle

Nasser, Heider ; Rédey, A. ; Yuzhakova, Tatiana ; Kovács, József. / In situ DRIFT study of nonoxidative methane reaction on Mo/SnO2 catalyst. In: Reaction Kinetics and Catalysis Letters. 2008 ; Vol. 94, No. 1. pp. 165-173.
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