In-flight epimerization of a bis-Tröger base

Ágnes Révész, Detlef Schröder, Tibor András Rokob, Martin Havlík, Bohumil Dolenský

Research output: Contribution to journalArticle

41 Citations (Scopus)

Abstract

(Graph Presented) Increased mobility is observed for the sodiated syn and anti isomers of bis-Tröger base 1 relative to that of the protonated variants. Ion-mobility measurements further demonstrate that the pseudo-epimerization of the bis-Tröger base proceeds by a proton-mediated ring opening rather than a retro-Diels-Alder sequence.

Original languageEnglish
Pages (from-to)2401-2404
Number of pages4
JournalAngewandte Chemie - International Edition
Volume50
Issue number10
DOIs
Publication statusPublished - Mar 1 2011

Keywords

  • Aggregation
  • Epimerization
  • Ion-mobility mass spectrometry
  • Sodium complexes
  • Tröger bases

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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