Impact of high π-density on the coordination properties of π-excess aromatic neutral σ2P ligands-P(π)-donor bonds to Ag + and HgCl2

Mohammed Ghalib, László Könczöl, László Nyulászi, Peter G. Jones, Gottfried J. Palm, Joachim W. Heinicke

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25 Citations (Scopus)

Abstract

Unprecedented coordination types of non-zerovalent d10 transition metals (AgX, HgCl2) by π-excess aromatic P=C ligands involving P(π)-donor bond contributions were detected by structural and quantum chemical studies.

Original languageEnglish
Pages (from-to)51-54
Number of pages4
JournalDalton Transactions
Volume43
Issue number1
DOIs
Publication statusPublished - Jan 7 2014

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ASJC Scopus subject areas

  • Inorganic Chemistry

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