Hydrogenolysis of n-hexane on Al2O3-supported Ir catalysts of various treatments

A. Majesté, S. Balcon, M. Guérin, C. Kappenstein, Z. Paál

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

A high-dispersion 1 wt% Ir/Al2O3 with 1 wt% Cl as well as its counterparts with 2 pressure or higher temperature), a "soft" transition from single to multiple rupture occurred. The multiplicity of rupture was most pronounced on the larger crystallites of the sintered sample, whereas a terminal rupture seemed to appear on the Cl-free high-dispersion sample. Whenever single hydrogenolysis prevailed, the fragment distribution showed a slight preference to propane formation.

Original languageEnglish
Pages (from-to)486-492
Number of pages7
JournalJournal of Catalysis
Volume187
Issue number2
Publication statusPublished - 1999

Fingerprint

hydrogenolysis
Hydrogenolysis
Hexane
Catalyst supports
catalysts
Propane
Crystallites
propane
crystallites
fragments
Temperature
temperature
n-hexane

Keywords

  • Cl in alumina
  • Hydrogenolysis
  • Ir/AlO
  • n-hexane

ASJC Scopus subject areas

  • Catalysis
  • Process Chemistry and Technology

Cite this

Majesté, A., Balcon, S., Guérin, M., Kappenstein, C., & Paál, Z. (1999). Hydrogenolysis of n-hexane on Al2O3-supported Ir catalysts of various treatments. Journal of Catalysis, 187(2), 486-492.

Hydrogenolysis of n-hexane on Al2O3-supported Ir catalysts of various treatments. / Majesté, A.; Balcon, S.; Guérin, M.; Kappenstein, C.; Paál, Z.

In: Journal of Catalysis, Vol. 187, No. 2, 1999, p. 486-492.

Research output: Contribution to journalArticle

Majesté, A, Balcon, S, Guérin, M, Kappenstein, C & Paál, Z 1999, 'Hydrogenolysis of n-hexane on Al2O3-supported Ir catalysts of various treatments', Journal of Catalysis, vol. 187, no. 2, pp. 486-492.
Majesté, A. ; Balcon, S. ; Guérin, M. ; Kappenstein, C. ; Paál, Z. / Hydrogenolysis of n-hexane on Al2O3-supported Ir catalysts of various treatments. In: Journal of Catalysis. 1999 ; Vol. 187, No. 2. pp. 486-492.
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