Hydrogenation of pyrrole derivatives - Part V. Poisoning effect of nitrogen on precious metal on carbon catalysts

László Hegedus, Tibor Máthé

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28 Citations (Scopus)

Abstract

Poisoning of different precious metals on carbon catalysts (Pd/C, Ru/C and Rh/C) was observed in the hydrogenation of some pyrrole derivatives, under mild reaction conditions, in non-acidic medium. In all reductions, the catalysts were poisoned by the hydrogenated products (pyrrolidines) more strongly than by the reactants (pyrroles). A comparison concerning poison sensitivity of the catalytic metals was also made.

Original languageEnglish
Pages (from-to)319-322
Number of pages4
JournalApplied Catalysis A: General
Volume226
Issue number1-2
DOIs
Publication statusPublished - Mar 28 2002

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Keywords

  • Hydrogenation
  • Palladium
  • Poisoning
  • Pyrroles
  • Pyrrolidines
  • Rhodium
  • Ruthenium

ASJC Scopus subject areas

  • Catalysis
  • Process Chemistry and Technology

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