Hydrogenation of carbon-carbon multiple bonds

Chemo-, regio- and stereo-selectivity

Árpád Molnár, A. Sárkány, M. Varga

Research output: Contribution to journalArticle

445 Citations (Scopus)

Abstract

Results of the last decade with respect to the selective hydrogenation of hydrocarbons with multiple unsaturation (dienes and alkynes) over heterogeneous palladium catalysts are reviewed. Factors such as metal dispersion, carbon deposits, and the use of promoters and additives controlling catalytic activities and chemo-, regio- and stereo-selectivity are discussed. A detailed treatment of the status of the selective removal of hydrocarbon impurities with multiple unsaturation from industrial feedstocks is also given.

Original languageEnglish
Pages (from-to)185-221
Number of pages37
JournalJournal of Molecular Catalysis A: Chemical
Volume173
Issue number1-2
DOIs
Publication statusPublished - Sep 10 2001

Fingerprint

Stereoselectivity
Hydrocarbons
Hydrogenation
hydrogenation
Carbon
hydrocarbons
selectivity
Alkynes
Catalyst selectivity
carbon
Palladium
dienes
alkynes
Feedstocks
catalytic activity
palladium
Catalyst activity
Deposits
Metals
deposits

Keywords

  • Acetylenes
  • Dienes
  • Palladium
  • Partial hydrogenation
  • Selectivity

ASJC Scopus subject areas

  • Catalysis
  • Process Chemistry and Technology

Cite this

Hydrogenation of carbon-carbon multiple bonds : Chemo-, regio- and stereo-selectivity. / Molnár, Árpád; Sárkány, A.; Varga, M.

In: Journal of Molecular Catalysis A: Chemical, Vol. 173, No. 1-2, 10.09.2001, p. 185-221.

Research output: Contribution to journalArticle

@article{1a03ce7d12d347808578ee71471ac30a,
title = "Hydrogenation of carbon-carbon multiple bonds: Chemo-, regio- and stereo-selectivity",
abstract = "Results of the last decade with respect to the selective hydrogenation of hydrocarbons with multiple unsaturation (dienes and alkynes) over heterogeneous palladium catalysts are reviewed. Factors such as metal dispersion, carbon deposits, and the use of promoters and additives controlling catalytic activities and chemo-, regio- and stereo-selectivity are discussed. A detailed treatment of the status of the selective removal of hydrocarbon impurities with multiple unsaturation from industrial feedstocks is also given.",
keywords = "Acetylenes, Dienes, Palladium, Partial hydrogenation, Selectivity",
author = "{\'A}rp{\'a}d Moln{\'a}r and A. S{\'a}rk{\'a}ny and M. Varga",
year = "2001",
month = "9",
day = "10",
doi = "10.1016/S1381-1169(01)00150-9",
language = "English",
volume = "173",
pages = "185--221",
journal = "Journal of Molecular Catalysis A: Chemical",
issn = "1381-1169",
publisher = "Elsevier",
number = "1-2",

}

TY - JOUR

T1 - Hydrogenation of carbon-carbon multiple bonds

T2 - Chemo-, regio- and stereo-selectivity

AU - Molnár, Árpád

AU - Sárkány, A.

AU - Varga, M.

PY - 2001/9/10

Y1 - 2001/9/10

N2 - Results of the last decade with respect to the selective hydrogenation of hydrocarbons with multiple unsaturation (dienes and alkynes) over heterogeneous palladium catalysts are reviewed. Factors such as metal dispersion, carbon deposits, and the use of promoters and additives controlling catalytic activities and chemo-, regio- and stereo-selectivity are discussed. A detailed treatment of the status of the selective removal of hydrocarbon impurities with multiple unsaturation from industrial feedstocks is also given.

AB - Results of the last decade with respect to the selective hydrogenation of hydrocarbons with multiple unsaturation (dienes and alkynes) over heterogeneous palladium catalysts are reviewed. Factors such as metal dispersion, carbon deposits, and the use of promoters and additives controlling catalytic activities and chemo-, regio- and stereo-selectivity are discussed. A detailed treatment of the status of the selective removal of hydrocarbon impurities with multiple unsaturation from industrial feedstocks is also given.

KW - Acetylenes

KW - Dienes

KW - Palladium

KW - Partial hydrogenation

KW - Selectivity

UR - http://www.scopus.com/inward/record.url?scp=0035840166&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0035840166&partnerID=8YFLogxK

U2 - 10.1016/S1381-1169(01)00150-9

DO - 10.1016/S1381-1169(01)00150-9

M3 - Article

VL - 173

SP - 185

EP - 221

JO - Journal of Molecular Catalysis A: Chemical

JF - Journal of Molecular Catalysis A: Chemical

SN - 1381-1169

IS - 1-2

ER -