Hydrogen pressure-dependence in the ring-opening reactions of substituted cyclopropanes over Rh/SiO2 catalyst

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Abstract

The hydrogen coverage and the structures of the reactants influence the selectivity and mechanism of the ring-opening reactions of ethyl-(ECP), cis-1,2-dimethyl-(cDMCP), trans1,2-dimethyl-(tDMCP), 1,1-dimethyl-(1, 1DMCP) and 1, 1, 2, 2-tetramethylcyclopropane (TMCP) over Rh/SiO2 catalyst; a new phenomenon was observed for the transformations of ECP, tDMCP and 1, 1DMCP, viz. the turnover frequency vs. H2 pressure functions pass through a minimum.

Original languageEnglish
Pages (from-to)229-235
Number of pages7
JournalCatalysis Letters
Volume5
Issue number2
DOIs
Publication statusPublished - Mar 1 1990

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Keywords

  • Hydrogenative ring-opening
  • Rh on silica catalyst
  • alkyl-substituted cyclopropanes
  • hydrogen pressure effect

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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