Hydrogen bonding in α-phenylethyl hydroperoxide

É Danóczy, S. Holly, G. Jalsovszky, D. Gá

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

The H-bonded associates of α-phenylethyl hydroperoxide (HROOH) were investigated in CCl4, at various concentrations (0.788 × 10-3-960 × 10-3 M) and temperatures (22-75°C), by using IR spectroscopic methods. A very stable intramolecular OH••π bond was observed with a low enthalpy value. Above a concentration of 50 × 10-3 M cyclic dimers and trimers were found, the latter with the lowest thermal stability. The corresponding thermodynamic parameters have been calculated.

Original languageEnglish
Pages (from-to)1190-1194
Number of pages5
JournalJournal of Physical Chemistry
Volume88
Issue number6
Publication statusPublished - 1984

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Dimers
Hydrogen Peroxide
Enthalpy
Hydrogen bonds
Thermodynamic stability
Thermodynamics
hydrogen
trimers
thermal stability
enthalpy
dimers
Temperature
thermodynamics
temperature

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

Cite this

Danóczy, É., Holly, S., Jalsovszky, G., & Gá, D. (1984). Hydrogen bonding in α-phenylethyl hydroperoxide. Journal of Physical Chemistry, 88(6), 1190-1194.

Hydrogen bonding in α-phenylethyl hydroperoxide. / Danóczy, É; Holly, S.; Jalsovszky, G.; Gá, D.

In: Journal of Physical Chemistry, Vol. 88, No. 6, 1984, p. 1190-1194.

Research output: Contribution to journalArticle

Danóczy, É, Holly, S, Jalsovszky, G & Gá, D 1984, 'Hydrogen bonding in α-phenylethyl hydroperoxide', Journal of Physical Chemistry, vol. 88, no. 6, pp. 1190-1194.
Danóczy É, Holly S, Jalsovszky G, Gá D. Hydrogen bonding in α-phenylethyl hydroperoxide. Journal of Physical Chemistry. 1984;88(6):1190-1194.
Danóczy, É ; Holly, S. ; Jalsovszky, G. ; Gá, D. / Hydrogen bonding in α-phenylethyl hydroperoxide. In: Journal of Physical Chemistry. 1984 ; Vol. 88, No. 6. pp. 1190-1194.
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