Hydrogen bonding in α-phenylethyl hydroperoxide

É Danóczy, S. Holly, G. Jalsovszky, D. Gá

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Abstract

The H-bonded associates of α-phenylethyl hydroperoxide (HROOH) were investigated in CCl4, at various concentrations (0.788 × 10-3-960 × 10-3 M) and temperatures (22-75°C), by using IR spectroscopic methods. A very stable intramolecular OH••π bond was observed with a low enthalpy value. Above a concentration of 50 × 10-3 M cyclic dimers and trimers were found, the latter with the lowest thermal stability. The corresponding thermodynamic parameters have been calculated.

Original languageEnglish
Pages (from-to)1190-1194
Number of pages5
JournalJournal of physical chemistry
Volume88
Issue number6
Publication statusPublished - Dec 1 1984

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ASJC Scopus subject areas

  • Engineering(all)
  • Physical and Theoretical Chemistry

Cite this

Danóczy, É., Holly, S., Jalsovszky, G., & Gá, D. (1984). Hydrogen bonding in α-phenylethyl hydroperoxide. Journal of physical chemistry, 88(6), 1190-1194.