Intermediates of spirosulfurane formations are prepared from carboxyaryl sulfides with chlorinating agent; the molecular structures determined by X-ray diffraction show disorted trigonal bipyramidal geometry about the sulfur atom with S+ ⋯ O=, S+ ⋯ Cl- and O-H ⋯ Cl- interactions.
|Number of pages||3|
|Journal||Journal of the Chemical Society, Chemical Communications|
|Publication status||Published - Dec 1 1992|
ASJC Scopus subject areas
- Molecular Medicine