Hydroformylation of chiral terpenes with PtCl(SnCl3)-(bis-phosphine) as catalyst

L. Kollár, J. Bakos, Bálint Heil, Péter Sándor, Gábor Szalontai

Research output: Contribution to journalArticle

36 Citations (Scopus)

Abstract

(+)-R-Limonene and (-)-R-carvone undergo hydroformylation in the presence of catalytic Pt-bisphosphine-SnCl2 systems to yield exclusively the linear products. The internal double bond and the carbonyl group remain intact in both substrates during the reaction. The variation of the diastereomeric composition of the aldehydes upon variation of the chelating phosphine in the catalyst has been investigated.

Original languageEnglish
Pages (from-to)147-152
Number of pages6
JournalJournal of Organometallic Chemistry
Volume385
Issue number1
DOIs
Publication statusPublished - Mar 13 1990

Fingerprint

phosphine
terpenes
Terpenes
Hydroformylation
Chelation
Aldehydes
phosphines
catalysts
Catalysts
Substrates
Chemical analysis
aldehydes
products
carvone
limonene

ASJC Scopus subject areas

  • Biochemistry
  • Chemical Engineering (miscellaneous)
  • Inorganic Chemistry
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Science (miscellaneous)
  • Materials Chemistry

Cite this

Hydroformylation of chiral terpenes with PtCl(SnCl3)-(bis-phosphine) as catalyst. / Kollár, L.; Bakos, J.; Heil, Bálint; Sándor, Péter; Szalontai, Gábor.

In: Journal of Organometallic Chemistry, Vol. 385, No. 1, 13.03.1990, p. 147-152.

Research output: Contribution to journalArticle

Kollár, L. ; Bakos, J. ; Heil, Bálint ; Sándor, Péter ; Szalontai, Gábor. / Hydroformylation of chiral terpenes with PtCl(SnCl3)-(bis-phosphine) as catalyst. In: Journal of Organometallic Chemistry. 1990 ; Vol. 385, No. 1. pp. 147-152.
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