Hydroformylation of chiral terpenes with PtCl(SnCl3)-(bis-phosphine) as catalyst

László Kollár, József Bakos, Bálint Heil, Péter Sándor, Gábor Szalontai

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Abstract

(+)-R-Limonene and (-)-R-carvone undergo hydroformylation in the presence of catalytic Pt-bisphosphine-SnCl2 systems to yield exclusively the linear products. The internal double bond and the carbonyl group remain intact in both substrates during the reaction. The variation of the diastereomeric composition of the aldehydes upon variation of the chelating phosphine in the catalyst has been investigated.

Original languageEnglish
Pages (from-to)147-152
Number of pages6
JournalJournal of Organometallic Chemistry
Volume385
Issue number1
DOIs
Publication statusPublished - Mar 13 1990

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ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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