Hydration of iron(II) ion in aqueous solutions

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

The hydration of several iron(II) compounds has been studied by the Mössbauer technique and the X-ray diffraction method. The similarity of the Mössbauer parameters (isomer shift, quadrupole splitting) of aqueous iron(II) salt solutions suggested that Fe2+ contrary to Fe3+ in the above solutions is present mainly in the form of the hexaaquo complex. Based on the analysis of X-ray data, however, the existence of moderate Fe(H2O)5A complex formation in addition to the dominating hexaaquo complexes in chloride and sulfate solutions could not be excluded.

Original languageEnglish
Pages (from-to)1223-1228
Number of pages6
JournalElectrochimica Acta
Volume33
Issue number9
DOIs
Publication statusPublished - Sep 1988

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Electrochemistry

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