HPLC studies on the organic subset of the oscillatory BZ reaction. 2. Two different types of malonyl radicals in the Ce4+-malonic acid reaction

Atchara Sirimungkala, Horst Dieter Försterling, Zoltan Noszticzius

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28 Citations (Scopus)

Abstract

Applying combined HPLC and NMR techniques, it was found that, besides the already known 1,1,2,2-ethanetetracarboxylic acid (ETA), monomalonyl malonate (MAMA) is also a product of the Ce4+-malonic acid reaction. This is indirect evidence that two different types of organic radicals are formed in the reaction: the alkyl and the carboxylato malonyl radicals. While ETA is a recombination product of two alkyl radicals, MAMA is formed in the recombination of one alkyl and one carboxylato radical.

Original languageEnglish
Pages (from-to)3051-3055
Number of pages5
JournalJournal of physical chemistry
Volume100
Issue number8
Publication statusPublished - Feb 22 1996

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ASJC Scopus subject areas

  • Engineering(all)
  • Physical and Theoretical Chemistry

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