HPLC analysis of the product distrtoution in the iodine-catalyzed methyl glycosidation of pentoses and 6-deoxyhexoses

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Abstract

The product distribution of the iodine-catalyzed methyl glycosidation of four pentoses (D-ribose, D-arabinose, D-xylose, and D-lyxose) and two 6-deoxyhexoses (L-rhamnose, and D-fucose) was studied by HPLC using an APS column (dihydrogen sulphate form) with different acetonitrile-water mobile phases. In agreement with earlier results, a temperature dependent on-column isomerization was observed for all the investigated aid oses, except for ribose. The first-eluted furanosides were followed by pyranosides, and the free sugars were eluted last with the highest retention volumes.

Original languageEnglish
Pages (from-to)359-368
Number of pages10
JournalJournal of Carbohydrate Chemistry
Volume17
Issue number3
DOIs
Publication statusPublished - Jan 1 1998

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry

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