Homogeneous hydrogenation of aqueous hydrogen carbonate to formate under mild conditions with water soluble rhodium(I)- and ruthenium(II)-phosphine catalysts

Ferenc Joó, Gábor Laurenczy, Péter Karády, János Elek, Levente Nádasdi, Raymond Roulet

Research output: Contribution to journalArticle

42 Citations (Scopus)

Abstract

Water-soluble rhodium(I)- and ruthenium(II)-tertiary phosphine complexes with meta-monosulphonated triphenylphosphine (TPPMS) and 1,3,5-triaza-7-phosphaadamantane (PTA) as ligands catalyze the hydrogenation of aqueous HCO3- to HCO2- under mild conditions. No amine additive is needed for good turnovers. CO2 accelerates the reactions with [RhCl(TPPMS)3] catalyst; however, it slightly inhibits the reductions catalyzed by [RuCl2(TPPMS)2]. Bicarbonate formed in the reaction of limestone with aqueous CO2 can also be used as starting material for formate production. Copyright (C) 2000 John Wiley and Sons, Ltd.

Original languageEnglish
Pages (from-to)857-859
Number of pages3
JournalApplied Organometallic Chemistry
Volume14
Issue number12
DOIs
Publication statusPublished - Dec 27 2000

    Fingerprint

Keywords

  • Aqueous organometallic catalysis
  • Carbon dioxide
  • Homogeneous catalysis
  • Hydrogenation
  • Rhodium
  • Ruthenium

ASJC Scopus subject areas

  • Chemistry(all)
  • Inorganic Chemistry

Cite this