Highly selective hydroformylation and dimerization reactions of 2-ferrocenylpropene

L. Kollár, Barbara Fliris

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Selective dimerization and hydroformylation of 2-ferrocenylpropene has been shown to take place in the presence of platinum- and rhodium-catalysts, respectively. The cyclic dimerization proceeds selectively by a homoannular pathway. The hydroformylation gives the less-branched formyl isomer with more than 90% regioselectivity. Some optical induction is observed in both reactions.

Original languageEnglish
Pages (from-to)117-123
Number of pages7
JournalJournal of Organometallic Chemistry
Volume441
Issue number1
DOIs
Publication statusPublished - Dec 1 1992

Fingerprint

Hydroformylation
Dimerization
dimerization
Regioselectivity
Rhodium
Platinum
rhodium
Isomers
induction
platinum
isomers
catalysts
Catalysts

ASJC Scopus subject areas

  • Biochemistry
  • Chemical Engineering (miscellaneous)
  • Inorganic Chemistry
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Science (miscellaneous)
  • Materials Chemistry

Cite this

Highly selective hydroformylation and dimerization reactions of 2-ferrocenylpropene. / Kollár, L.; Fliris, Barbara.

In: Journal of Organometallic Chemistry, Vol. 441, No. 1, 01.12.1992, p. 117-123.

Research output: Contribution to journalArticle

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