High temperature electron diffraction investigation and the bending vibrational frequency of cobalt (II) chloride

J. Tremmel, A. A. Ivanov, Gy Schultz, I. Hargittai, S. J. Cyvin, A. Eriksson

Research output: Contribution to journalArticle

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Abstract

The structure of CoCl2 was studied by high-temperature gas electron diffraction. The linear shrinkage effect was determined in particular and compared to values calculated by spectroscopical methods. By this approach the v2 vibrational frequency was determined to be 78 ± 8 cm -1, which is significantly larger than a previous estimate from the literature. The present; value is fairly well compatible with a recent matrix-isolation infrared frequency, viz. 94 cm-1.

Original languageEnglish
Pages (from-to)533-534
Number of pages2
JournalChemical Physics Letters
Volume23
Issue number4
DOIs
Publication statusPublished - Dec 15 1973

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Vibrational spectra
Electron diffraction
cobalt
electron diffraction
chlorides
Infrared radiation
high temperature gases
shrinkage
isolation
Temperature
estimates
matrices
cobaltous chloride

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Condensed Matter Physics
  • Atomic and Molecular Physics, and Optics
  • Surfaces and Interfaces

Cite this

High temperature electron diffraction investigation and the bending vibrational frequency of cobalt (II) chloride. / Tremmel, J.; Ivanov, A. A.; Schultz, Gy; Hargittai, I.; Cyvin, S. J.; Eriksson, A.

In: Chemical Physics Letters, Vol. 23, No. 4, 15.12.1973, p. 533-534.

Research output: Contribution to journalArticle

Tremmel, J. ; Ivanov, A. A. ; Schultz, Gy ; Hargittai, I. ; Cyvin, S. J. ; Eriksson, A. / High temperature electron diffraction investigation and the bending vibrational frequency of cobalt (II) chloride. In: Chemical Physics Letters. 1973 ; Vol. 23, No. 4. pp. 533-534.
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