High-pressure melting curves and liquid-liquid phase transition

A. R. Imre, Sylwester J. Rzoska

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

Breaks on the melting lines in the pressure-temperature (Tm(P)) space are often handled as a hallmark of a liquid-liquid phase transition in pure materials. In this paper it is shown that there is no one-to-one agreement between these virtual breaks and liquid-liquid transitions. Four melting curves are analyzed; selenium, phosphorus, carbon and nitrogen. It is shown that a modified form of the Simon-Glatzel equation can describe experimental data, without introducing any break, demonstrating that the shape of the melting line is not an evidence for any further phase transition.

Original languageEnglish
Pages (from-to)527-530
Number of pages4
JournalAdvanced Science Letters
Volume3
Issue number4
DOIs
Publication statusPublished - Dec 1 2010

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ASJC Scopus subject areas

  • Computer Science(all)
  • Health(social science)
  • Mathematics(all)
  • Education
  • Environmental Science(all)
  • Engineering(all)
  • Energy(all)

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