Heterosite reactivity of cobalt-rhodium mixed- metal clusters

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

It has been established that reactions of cobalt-rhodium mixed-metal clusters with nucleophiles such as PEt3, THF, MeCN and Cl- occur on the rhodium site, with alkynes on the cobalt site. Several reversible tetranuclear-dinuclear transformations were observed with preferential retainment of the cobalt-rhodium bond.

Original languageEnglish
Pages (from-to)2345-2349
Number of pages5
JournalPolyhedron
Volume7
Issue number22-23
DOIs
Publication statusPublished - 1988

Fingerprint

Rhodium
metal clusters
Cobalt
rhodium
cobalt
reactivity
Metals
Nucleophiles
Alkynes
nucleophiles
alkynes

ASJC Scopus subject areas

  • Biochemistry
  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

Heterosite reactivity of cobalt-rhodium mixed- metal clusters. / Horváth, I.

In: Polyhedron, Vol. 7, No. 22-23, 1988, p. 2345-2349.

Research output: Contribution to journalArticle

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