Heterogeneous asymmetric reactions, 22. β-Isocinchona alkaloids in enantioselective hydrogenations

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Abstract

The enantioselective hydrogenation of ethyl pyruvate to (S)-ethyl lactate over Pt/Al2O3 catalyst was investigated using the new modifier β-isocinchonine (40% ee) which has oxazatwistane structure. These studies supply additional evidence for the widely accepted reaction mechanism.

Original languageEnglish
Pages (from-to)99-108
Number of pages10
JournalReaction Kinetics and Catalysis Letters
Volume71
Issue number1
DOIs
Publication statusPublished - Jan 1 2000

Keywords

  • Enantioselective
  • Ethyl pyruvate
  • Hydrogenation
  • β-isocinchonine

ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry

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