Heterocyclische β-enamino-ester-V. Spektroskopische untersuchungen zur struktur heterocyclischer β-enamino-ester

H. Wamhoff, H. W. Dürbeck, P. Sohár

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UV, IR, and NMR spectra of 23 β-enamino-esters are described. The bathochromic shift in the UV spectra confirms a considerable π-electron delocalization. From the IR spectra follows, that the 2-standing amino function is not chelated to the neighbouring ester carbonyl. Deuterium exchange experiments show, that the bands of the enamino-carbonyl group must be considered as absorptions of group frequencies EI, EII and EIII, The NMR spectra reveal, that all potential tautomeric compounds described exist predominantly in the enamine form. The amine proton resonance position confirms the unchelated form. From the spectroscopic data certain correlations regarding the stability and chemical properties of these compounds can be drawn.

Original languageEnglish
Pages (from-to)5873-5891
Number of pages19
Issue number23
Publication statusPublished - 1971


ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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