Green chemical tools in organophosphorus chemistry-organophosphorus tools in green chemistry

G. Keglevich, A. Grün, Erika Bálint, Nóra Zs Kiss, Rita Kovács, István G. Molnár, Zsófia Blastik, R. Viola Tóth, András Fehérvári, István Csontos

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

A variety of reactions including esterifications, alkylations, additions, cycloadditions, fragmentations, and condensations were carried out under microwave MW-assisted and solventless conditions, occasionally in ionic liquids (ILs). In a few cases, MW was synergic with phase transfer catalysis or could substitute it. A variety of P(III) ligands were developed and converted to Pt(II) complexes that can be used as catalysts. Finally, phosphorylations and the Kabachnik-Fields reaction were monitored and optimized by an on-line method, in situ Fourier transform IR spectroscopy.

Original languageEnglish
Pages (from-to)613-620
Number of pages8
JournalPhosphorus, Sulfur and Silicon and Related Elements
Volume186
Issue number4
DOIs
Publication statusPublished - 2011

Fingerprint

Ionic Liquids
Phosphorylation
Cycloaddition
Esterification
Alkylation
Cycloaddition Reaction
Fourier Analysis
Microwaves
Catalysis
Condensation
Infrared spectroscopy
Spectrum Analysis
Fourier transforms
Ligands
Catalysts

Keywords

  • Green chemistry
  • In situ Fourier transform IR spectroscopy
  • MW-assisted organic synthesis
  • Organophosphorus chemistry
  • Phase transfer catalysis
  • Pt(II)-P(III) complexes

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry
  • Biochemistry

Cite this

Green chemical tools in organophosphorus chemistry-organophosphorus tools in green chemistry. / Keglevich, G.; Grün, A.; Bálint, Erika; Kiss, Nóra Zs; Kovács, Rita; Molnár, István G.; Blastik, Zsófia; Tóth, R. Viola; Fehérvári, András; Csontos, István.

In: Phosphorus, Sulfur and Silicon and Related Elements, Vol. 186, No. 4, 2011, p. 613-620.

Research output: Contribution to journalArticle

Keglevich, G, Grün, A, Bálint, E, Kiss, NZ, Kovács, R, Molnár, IG, Blastik, Z, Tóth, RV, Fehérvári, A & Csontos, I 2011, 'Green chemical tools in organophosphorus chemistry-organophosphorus tools in green chemistry', Phosphorus, Sulfur and Silicon and Related Elements, vol. 186, no. 4, pp. 613-620. https://doi.org/10.1080/10426507.2010.507725
Keglevich, G. ; Grün, A. ; Bálint, Erika ; Kiss, Nóra Zs ; Kovács, Rita ; Molnár, István G. ; Blastik, Zsófia ; Tóth, R. Viola ; Fehérvári, András ; Csontos, István. / Green chemical tools in organophosphorus chemistry-organophosphorus tools in green chemistry. In: Phosphorus, Sulfur and Silicon and Related Elements. 2011 ; Vol. 186, No. 4. pp. 613-620.
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