Glycoside synthesis with anomeric 1-N-glycobiosyl-1,2,3-triazoles

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Abstract

1,3-Dipolar cycloaddition of the acetylated 1,2-trans-and 1,2-cis-cellobiosyl, -lactosyl, -maltosyl, and -melibiosyl azides with various acetylenedicarboxylic acid esters gave the corresponding 1-N-glycobiosyl-1,2,3-triazoles (1a,b,c-8a,b,c) which have been used as glycosyl donors for the synthesis of oligosaccharides (15-17) and an anthracycline type antibiotic (18).

Original languageEnglish
Pages (from-to)465-483
Number of pages19
JournalJournal of Carbohydrate Chemistry
Volume15
Issue number4
Publication statusPublished - Dec 1 1996

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ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry

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