FT-IR and FT-Raman studies on tetranuclear oxo-centered carboxylate complexes of zinc(II)

O. Berkesi, I. Dreveni, J. A. Andor, U. A. Jayasooriya, R. D. Cannon, J. Mink

Research output: Contribution to journalConference article

Abstract

A selection of stable Zn4O(RCOO)6 complexes have been studied by FT-IR and FT-Raman spectroscopy. Polarised FT-Raman studies of two samples, which were in liquid state at ambient temperature, have also been completed. An attempt was made to construct the kinetic energy matrix for a simplified model involving 29 atoms with Td symmetry. A set of symmetry coordinates was chosen to describe the vibrational behaviour of the molecule and serve as a base for future force-field calculations. The characteristic frequencies of A1 and T2 species were assigned. Some of the E modes were also obtained.

Original languageEnglish
Pages (from-to)220-221
Number of pages2
JournalProceedings of SPIE - The International Society for Optical Engineering
Volume2089
DOIs
Publication statusPublished - Jan 31 1994
Event9th International Conference on Fourier Transform Spectroscopy 1993 - Calgary, Canada
Duration: Aug 23 1993Aug 27 1993

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Computer Science Applications
  • Applied Mathematics
  • Electrical and Electronic Engineering

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