Fourier transform infrared spectroscopic study on the molecular structure of bis(butanoato) zinc(II) and μ4-oxohexa-μ-butanoatotetrazinc(II) complexes

I. Dreveni, O. Berkesi, I. Janovics, J. A. Andor, J. Mink

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

The bis(butanoato)zinc(II) and μ4-oxohexa-μ-butanoatotetrazinc(II) complexes of n- and isobutanoic acids {Zn[CH3(CH2)2COO]2, Zn4O[CH3(CH2)2COO]6, Zn[(CH3)2CHCOO]2 and Zn4O[(CH3)2CHCOO]6} were prepared and their infrared spectra recorded in the solid state and in carbon tetrachloride solution. Both forms of zinc butanoates, i.e., the bis(carboxylato) and oxo salts were found to exist as tetranuclear oxozinc carboxylates in carbon tetrachloride solution as a result of the equilibrium {A figure is presented} The oxozinc butanoates decomposed to bis(carboxylato) salts and zinc oxide during crystallization: {A figure is presented} Three fundamental types of structure were distinguished and their structural and chemical changes could clearly be monitored by means of Fourier transform infrared spectroscopy.

Original languageEnglish
Pages (from-to)205-209
Number of pages5
JournalVibrational Spectroscopy
Volume2
Issue number4
DOIs
Publication statusPublished - Dec 12 1991

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Carbon Tetrachloride
Molecular structure
Zinc
Fourier transforms
Salts
Infrared radiation
Zinc Oxide
Crystallization
Acids

Keywords

  • Infrared spectrometry
  • Zinc butanoates

ASJC Scopus subject areas

  • Analytical Chemistry
  • Spectroscopy

Cite this

Fourier transform infrared spectroscopic study on the molecular structure of bis(butanoato) zinc(II) and μ4-oxohexa-μ-butanoatotetrazinc(II) complexes. / Dreveni, I.; Berkesi, O.; Janovics, I.; Andor, J. A.; Mink, J.

In: Vibrational Spectroscopy, Vol. 2, No. 4, 12.12.1991, p. 205-209.

Research output: Contribution to journalArticle

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AB - The bis(butanoato)zinc(II) and μ4-oxohexa-μ-butanoatotetrazinc(II) complexes of n- and isobutanoic acids {Zn[CH3(CH2)2COO]2, Zn4O[CH3(CH2)2COO]6, Zn[(CH3)2CHCOO]2 and Zn4O[(CH3)2CHCOO]6} were prepared and their infrared spectra recorded in the solid state and in carbon tetrachloride solution. Both forms of zinc butanoates, i.e., the bis(carboxylato) and oxo salts were found to exist as tetranuclear oxozinc carboxylates in carbon tetrachloride solution as a result of the equilibrium {A figure is presented} The oxozinc butanoates decomposed to bis(carboxylato) salts and zinc oxide during crystallization: {A figure is presented} Three fundamental types of structure were distinguished and their structural and chemical changes could clearly be monitored by means of Fourier transform infrared spectroscopy.

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