Four consecutive reactions in one pot: Cascade formation of an unprecedented triphosphatricyclo[3.2.1.02,7]oct-3-ene

Steven Giese, Dániel Buzsáki, László Nyulászi, Christian Müller

Research output: Contribution to journalArticle

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Abstract

A hitherto unknown triphosphatricyclo[3.2.1.02,7]oct-3-ene was obtained in high yield by a total of four consecutive pericyclic reactions from di-2-pyrone and excess TMS-CP. DFT calculations gave insight into the reaction mechanism. The chiral phosphorus cage readily forms coordination compounds with Au(i) and Cu(i).

Original languageEnglish
Pages (from-to)13812-13815
Number of pages4
JournalChemical Communications
Volume55
Issue number92
DOIs
Publication statusPublished - Jan 1 2019

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ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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