Formation of radical cations and dose response of α-terthiophene-cellulose triacetate films irradiated by electrons and gamma rays

S. S. Emmi, E. Takács, P. Ceroni, M. D'Angelantonio, M. Lavalle, P. G. Fuochi, A. Kovács

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

The radiation-induced UV-vis spectrum of α-terthiophene radical cation in solid is reported. The radical cation initiates an oligomerization in the CTA matrix producing permanently coloured conjugated polarons. The specific net absorbance at 465nm is linearly related with dose up to 2×106Gy, for electrons and gamma irradiation. The decrease of the UV typical absorption (355nm) and of four IR bands of α-terthiophene is linear with dose, as well. Although sensitivity is influenced by dose rate, it turned out that a linear relationship holds between sensitivity and log dose rate, in the range from 2 to 105Gy/min. These findings suggest a potential application of the system for dosimetric purposes over a wide range of dose and dose rate.

Original languageEnglish
Pages (from-to)53-58
Number of pages6
JournalRadiation Physics and Chemistry
Volume63
Issue number1
DOIs
Publication statusPublished - 2002

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cellulose
rays
gamma rays
cations
dosage
electrons
sensitivity
polarons
irradiation
radiation
matrices

Keywords

  • Conjugated systems
  • CTA
  • Dosimetry
  • Electron beams
  • Film dosimeter
  • Gamma-rays
  • Oligothiophenes
  • Radiochromic dosimeters
  • Solid state oligomerization
  • Terthiophene radical cations

ASJC Scopus subject areas

  • Radiation

Cite this

Formation of radical cations and dose response of α-terthiophene-cellulose triacetate films irradiated by electrons and gamma rays. / Emmi, S. S.; Takács, E.; Ceroni, P.; D'Angelantonio, M.; Lavalle, M.; Fuochi, P. G.; Kovács, A.

In: Radiation Physics and Chemistry, Vol. 63, No. 1, 2002, p. 53-58.

Research output: Contribution to journalArticle

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AU - Emmi, S. S.

AU - Takács, E.

AU - Ceroni, P.

AU - D'Angelantonio, M.

AU - Lavalle, M.

AU - Fuochi, P. G.

AU - Kovács, A.

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N2 - The radiation-induced UV-vis spectrum of α-terthiophene radical cation in solid is reported. The radical cation initiates an oligomerization in the CTA matrix producing permanently coloured conjugated polarons. The specific net absorbance at 465nm is linearly related with dose up to 2×106Gy, for electrons and gamma irradiation. The decrease of the UV typical absorption (355nm) and of four IR bands of α-terthiophene is linear with dose, as well. Although sensitivity is influenced by dose rate, it turned out that a linear relationship holds between sensitivity and log dose rate, in the range from 2 to 105Gy/min. These findings suggest a potential application of the system for dosimetric purposes over a wide range of dose and dose rate.

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