Formation of Platinum-Tin Bond by Tin(II)Chloride Insertion

László Kollár, Serafino Gladiali, Manuel Jimenez Tenorio, Walter Weissensteiner

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

The first 119Sn NMR evidence for the presence of direct platinum-tin bond in solution has been obtained for PtCl(SnCl3)(bdpp) complex (bdpp = (2S,4S(-2,4-bis(diphenylphosphino)pentane). Various PtCl2(L2) complexes (L2 = hetero-bidentate P-P, P-O, P-N, P-S chelating ligands) have been reacted with tin(II)chloride resulting in the formation of the corresponding PtCl(SnCl3)(L2) derivatives. Tin(II)chloride has been inserted into the Pt-Cl bond trans to the harder donor atom of the L2 ligand.

Original languageEnglish
Pages (from-to)321-328
Number of pages8
JournalJournal of Cluster Science
Volume9
Issue number3
DOIs
Publication statusPublished - Jan 1 1998

Keywords

  • Insertion
  • NMR
  • Platinum
  • Platinum-tin bond
  • Tin(II)chloride

ASJC Scopus subject areas

  • Biochemistry
  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Fingerprint Dive into the research topics of 'Formation of Platinum-Tin Bond by Tin(II)Chloride Insertion'. Together they form a unique fingerprint.

  • Cite this