Formation of a new ring system: Tetrazolo[5,1-f][1,2]azaborinin

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

Phenothiazinyldienes obtained from tetrazolopyridinium salts and phenothiazine derivatives were subjected to reduction by borane-dimethyl sulfide in THF. Structure elucidation of the products revealed that one of the olefinic bond underwent reduction and, furthermore, borane addition at the double bond took place to yield derivatives of tetrazolo[5,1-f][1,2]azaborinin as a new fused ring system involving a bridge-head nitrogen atom. The new products have been synthesized and characterized by X-ray analysis, solution and solid-state NMR.

Original languageEnglish
Pages (from-to)2673-2678
Number of pages6
JournalJournal of Organometallic Chemistry
Volume695
Issue number24
DOIs
Publication statusPublished - Nov 15 2010

Keywords

  • Azaborinin
  • Cyclization
  • Phenothiazine
  • Single crystal
  • Solid-state NMR
  • X-ray

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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