Formation, Characterization, and Reactivity of a Nonheme Oxoiron(IV) Complex Derived from the Chiral Pentadentate Ligand asN4Py

Dóra Lakk-Bogáth, Róbert Csonka, Gábor Speier, Marius Réglier, A. Jalila Simaan, Jean Valère Naubron, Michel Giorgi, K. Lázár, József Kaizer

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

The chiral pentadentate low-spin (S = 1) oxoiron(IV) complex [FeIV(O)(asN4Py)]2+ (2) was synthesized and spectroscopically characterized. Its formation kinetics, reactivity, and (enantio)selectivity in an oxygen-atom-transfer reaction was investigated in detail and compared to a similar pentadentate ligand-containing system.

Original languageEnglish
Pages (from-to)10090-10093
Number of pages4
JournalInorganic Chemistry
Volume55
Issue number20
DOIs
Publication statusPublished - Oct 17 2016

    Fingerprint

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

Cite this

Lakk-Bogáth, D., Csonka, R., Speier, G., Réglier, M., Simaan, A. J., Naubron, J. V., Giorgi, M., Lázár, K., & Kaizer, J. (2016). Formation, Characterization, and Reactivity of a Nonheme Oxoiron(IV) Complex Derived from the Chiral Pentadentate Ligand asN4Py. Inorganic Chemistry, 55(20), 10090-10093. https://doi.org/10.1021/acs.inorgchem.6b01089