Formation and Solid State Structures of Highly Crystalline Guanidinium Salts of Sulfonated Tertiary Phosphanes

Ágnes Kathó, Attila C. Bényei, Ferenc Joó, Maria Sági

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13 Citations (Scopus)

Abstract

Formation of highly crystalline guanidinium salts of sulfonated triphenylphosphane derivatives is demonstrated as a general method for obtaining samples suitable for single crystal X-ray structural characterization. The structures of sulfonated phosphane ligands 1-5 have been determined. Extensive hydrogen bond networks between guanidinium N-H donors and -SO3 oxygens as acceptors and/or π-π interactions stabilize the structures.

Original languageEnglish
Pages (from-to)278-282
Number of pages5
JournalAdvanced Synthesis and Catalysis
Volume344
Issue number3-4
DOIs
Publication statusPublished - May 1 2002

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Keywords

  • Hydrogen bonds
  • Phosphanes
  • Water-soluble ligands
  • X-ray analysis

ASJC Scopus subject areas

  • Catalysis
  • Organic Chemistry

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