### Abstract

Force constants of dimethylmercury are calculated using the vibrational frequencies of gaseous (CH_{3})_{2}Hg and (CD_{3})_{2}Hg. A force constant calculation utilizing the generalised inverse matrix procedure is discussed briefly. Assuming a free rotational model, the force field is introduced as a trigonometrical function of the torsional angle γ; the time variant corrections of vibrational frequencies and normal coordinate vectors which this involves are investigated.

Original language | English |
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Pages (from-to) | 1-14 |

Number of pages | 14 |

Journal | Journal of Organometallic Chemistry |

Volume | 66 |

Issue number | 1 |

DOIs | |

Publication status | Published - Feb 14 1974 |

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### ASJC Scopus subject areas

- Biochemistry
- Chemical Engineering (miscellaneous)
- Inorganic Chemistry
- Organic Chemistry
- Physical and Theoretical Chemistry
- Materials Science (miscellaneous)
- Materials Chemistry

### Cite this

*Journal of Organometallic Chemistry*,

*66*(1), 1-14. https://doi.org/10.1016/S0022-328X(00)93881-6

**Force constant calculations for dimethylmercury.** / Mink, J.; Gellai, B.

Research output: Contribution to journal › Article

*Journal of Organometallic Chemistry*, vol. 66, no. 1, pp. 1-14. https://doi.org/10.1016/S0022-328X(00)93881-6

}

TY - JOUR

T1 - Force constant calculations for dimethylmercury

AU - Mink, J.

AU - Gellai, B.

PY - 1974/2/14

Y1 - 1974/2/14

N2 - Force constants of dimethylmercury are calculated using the vibrational frequencies of gaseous (CH3)2Hg and (CD3)2Hg. A force constant calculation utilizing the generalised inverse matrix procedure is discussed briefly. Assuming a free rotational model, the force field is introduced as a trigonometrical function of the torsional angle γ; the time variant corrections of vibrational frequencies and normal coordinate vectors which this involves are investigated.

AB - Force constants of dimethylmercury are calculated using the vibrational frequencies of gaseous (CH3)2Hg and (CD3)2Hg. A force constant calculation utilizing the generalised inverse matrix procedure is discussed briefly. Assuming a free rotational model, the force field is introduced as a trigonometrical function of the torsional angle γ; the time variant corrections of vibrational frequencies and normal coordinate vectors which this involves are investigated.

UR - http://www.scopus.com/inward/record.url?scp=0042942085&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0042942085&partnerID=8YFLogxK

U2 - 10.1016/S0022-328X(00)93881-6

DO - 10.1016/S0022-328X(00)93881-6

M3 - Article

VL - 66

SP - 1

EP - 14

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

SN - 0022-328X

IS - 1

ER -