Force constant calculations for dimethylmercury

J. Mink, B. Gellai

Research output: Contribution to journalArticle

26 Citations (Scopus)

Abstract

Force constants of dimethylmercury are calculated using the vibrational frequencies of gaseous (CH3)2Hg and (CD3)2Hg. A force constant calculation utilizing the generalised inverse matrix procedure is discussed briefly. Assuming a free rotational model, the force field is introduced as a trigonometrical function of the torsional angle γ; the time variant corrections of vibrational frequencies and normal coordinate vectors which this involves are investigated.

Original languageEnglish
Pages (from-to)1-14
Number of pages14
JournalJournal of Organometallic Chemistry
Volume66
Issue number1
DOIs
Publication statusPublished - Feb 14 1974

Fingerprint

Vibrational spectra
field theory (physics)
matrices
dimethyl mercury

ASJC Scopus subject areas

  • Biochemistry
  • Chemical Engineering (miscellaneous)
  • Inorganic Chemistry
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Science (miscellaneous)
  • Materials Chemistry

Cite this

Force constant calculations for dimethylmercury. / Mink, J.; Gellai, B.

In: Journal of Organometallic Chemistry, Vol. 66, No. 1, 14.02.1974, p. 1-14.

Research output: Contribution to journalArticle

@article{a476ef4db85e4bd58825105488dc075a,
title = "Force constant calculations for dimethylmercury",
abstract = "Force constants of dimethylmercury are calculated using the vibrational frequencies of gaseous (CH3)2Hg and (CD3)2Hg. A force constant calculation utilizing the generalised inverse matrix procedure is discussed briefly. Assuming a free rotational model, the force field is introduced as a trigonometrical function of the torsional angle γ; the time variant corrections of vibrational frequencies and normal coordinate vectors which this involves are investigated.",
author = "J. Mink and B. Gellai",
year = "1974",
month = "2",
day = "14",
doi = "10.1016/S0022-328X(00)93881-6",
language = "English",
volume = "66",
pages = "1--14",
journal = "Journal of Organometallic Chemistry",
issn = "0022-328X",
publisher = "Elsevier",
number = "1",

}

TY - JOUR

T1 - Force constant calculations for dimethylmercury

AU - Mink, J.

AU - Gellai, B.

PY - 1974/2/14

Y1 - 1974/2/14

N2 - Force constants of dimethylmercury are calculated using the vibrational frequencies of gaseous (CH3)2Hg and (CD3)2Hg. A force constant calculation utilizing the generalised inverse matrix procedure is discussed briefly. Assuming a free rotational model, the force field is introduced as a trigonometrical function of the torsional angle γ; the time variant corrections of vibrational frequencies and normal coordinate vectors which this involves are investigated.

AB - Force constants of dimethylmercury are calculated using the vibrational frequencies of gaseous (CH3)2Hg and (CD3)2Hg. A force constant calculation utilizing the generalised inverse matrix procedure is discussed briefly. Assuming a free rotational model, the force field is introduced as a trigonometrical function of the torsional angle γ; the time variant corrections of vibrational frequencies and normal coordinate vectors which this involves are investigated.

UR - http://www.scopus.com/inward/record.url?scp=0042942085&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0042942085&partnerID=8YFLogxK

U2 - 10.1016/S0022-328X(00)93881-6

DO - 10.1016/S0022-328X(00)93881-6

M3 - Article

VL - 66

SP - 1

EP - 14

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

SN - 0022-328X

IS - 1

ER -