Force constant calculations for dimethylmercury

J. Mink, B. Gellai

Research output: Contribution to journalArticle

26 Citations (Scopus)

Abstract

Force constants of dimethylmercury are calculated using the vibrational frequencies of gaseous (CH3)2Hg and (CD3)2Hg. A force constant calculation utilizing the generalised inverse matrix procedure is discussed briefly. Assuming a free rotational model, the force field is introduced as a trigonometrical function of the torsional angle γ; the time variant corrections of vibrational frequencies and normal coordinate vectors which this involves are investigated.

Original languageEnglish
Pages (from-to)1-14
Number of pages14
JournalJournal of Organometallic Chemistry
Volume66
Issue number1
DOIs
Publication statusPublished - Feb 14 1974

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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