Fluid inclusion evidence for magmatic silicate/saline/CO2 immiscibility and geochemistry of alkaline xenoliths from Ventotene Island, Italy

B. De Vivo, K. Török, R. A. Ayuso, A. Lima, L. Lirer

Research output: Contribution to journalArticle

40 Citations (Scopus)

Abstract

Fluid and melt inclusions and geochemical features of alkali syenite, mafic, and ultramafic cumulate xenoliths in the last ignimbritic event (volcanism up to 300 ky.b.P.) at the island of Ventotene in the Pontine archipelago (Gaeta Gulf) were investigated to establish the genesis and evolution of the fluids trapped in the inclusions. Ranges in lead isotopic compositions of the xenoliths as a group are narrow: 206Pb/204Pb:18.778-18.864; 207Pb/204Pb:15.641-15.701; 208Pb/204Pb:38.858-39.090; the values overlap among the groups, implying that the xenoliths are closely related. The xenoliths straddle the best-fit line describing the regional NW-SE variation of values for uranogenic Pb in volcanic rocks from the Roman alkaline province. The similarity between the xenoliths and volcanic rocks permits the interpretation that the xenoliths are representative of the source region of the volcanic rocks, residues after partial melting of the source region or fractional crystallization of the volcanic rocks, or even that the xenoliths represent assimilants obtained during the evolution of the magmas that produced the volcanic rocks. Xenoliths belonging to the ultramafic-mafic cumulate group contain only silicate melt inclusions ± vapor bubble ± droplets of an opaque phase and rarely some CO2 trapped in silicate melt inclusions. Xenoliths in the alkali syenite group have three types of fluid inclusions: (1) single phase vapor and silicate melt inclusions; (2) two-phase silicate melt + salt, silicate melt + CO2 (V), aqueous (L + V), and silicate melt + vapor inclusions, and (3) three-phase and multiphase inclusions: CO2 (L) + CO2 (V) + H2O; silicate melt + saline melt + H2O ± birefringent or opaque trapped minerals; H2O + salt + silicate glass ± birefringent trapped minerals. During heating experiments, melting of salt occurs at temperatures from 565 to 815°C, depending on the water content of the inclusions. Homogenization of the vapor bubble occurs from 850-1160°C, and complete melting of the silicate glass at about 950°C. The highly variable proportions of the individual phases in the silicate melt + salt + H2O inclusions and the coexistence of silicate melt + CO2 inclusions indicates immiscibility during the crystallization of the magma. Primary and secondary CO2 inclusions in the alkali syenite suite indicate lower densities (from 0.10 to 0.22 g/cm3) than those resulting from primary CO2 inclusions in the gabbroic suite (from 0.34 to 0.42 g/cm3). The P-T trajectory of the probable fluid evolution path shows that the crystallization of gabbro occurred between ∼1 and 1.4 kbars, whereas alkali syenite crystallized between ∼200 and 400 bars. The secondary H2O inclusions in alkali syenite were trapped in the later stages of the hydrothermal process and at much lower temperatures (130-290°C), but at pressures relatively close to those of alkali syenite crystallization. The almost isobaric conditions during the final stage of the fluid evolution path are explained by the very shallow emplacement of the alkali syenite intrusive body.

Original languageEnglish
Pages (from-to)2941-2953
Number of pages13
JournalGeochimica et Cosmochimica Acta
Volume59
Issue number14
DOIs
Publication statusPublished - 1995

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Silicates
immiscibility
Geochemistry
silicate melt
fluid inclusion
syenite
silicate
Solubility
geochemistry
Fluids
Alkalies
melt inclusion
Volcanic rocks
volcanic rock
salt
Crystallization
crystallization
cumulate
Salts
Vapors

ASJC Scopus subject areas

  • Geochemistry and Petrology

Cite this

Fluid inclusion evidence for magmatic silicate/saline/CO2 immiscibility and geochemistry of alkaline xenoliths from Ventotene Island, Italy. / De Vivo, B.; Török, K.; Ayuso, R. A.; Lima, A.; Lirer, L.

In: Geochimica et Cosmochimica Acta, Vol. 59, No. 14, 1995, p. 2941-2953.

Research output: Contribution to journalArticle

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abstract = "Fluid and melt inclusions and geochemical features of alkali syenite, mafic, and ultramafic cumulate xenoliths in the last ignimbritic event (volcanism up to 300 ky.b.P.) at the island of Ventotene in the Pontine archipelago (Gaeta Gulf) were investigated to establish the genesis and evolution of the fluids trapped in the inclusions. Ranges in lead isotopic compositions of the xenoliths as a group are narrow: 206Pb/204Pb:18.778-18.864; 207Pb/204Pb:15.641-15.701; 208Pb/204Pb:38.858-39.090; the values overlap among the groups, implying that the xenoliths are closely related. The xenoliths straddle the best-fit line describing the regional NW-SE variation of values for uranogenic Pb in volcanic rocks from the Roman alkaline province. The similarity between the xenoliths and volcanic rocks permits the interpretation that the xenoliths are representative of the source region of the volcanic rocks, residues after partial melting of the source region or fractional crystallization of the volcanic rocks, or even that the xenoliths represent assimilants obtained during the evolution of the magmas that produced the volcanic rocks. Xenoliths belonging to the ultramafic-mafic cumulate group contain only silicate melt inclusions ± vapor bubble ± droplets of an opaque phase and rarely some CO2 trapped in silicate melt inclusions. Xenoliths in the alkali syenite group have three types of fluid inclusions: (1) single phase vapor and silicate melt inclusions; (2) two-phase silicate melt + salt, silicate melt + CO2 (V), aqueous (L + V), and silicate melt + vapor inclusions, and (3) three-phase and multiphase inclusions: CO2 (L) + CO2 (V) + H2O; silicate melt + saline melt + H2O ± birefringent or opaque trapped minerals; H2O + salt + silicate glass ± birefringent trapped minerals. During heating experiments, melting of salt occurs at temperatures from 565 to 815°C, depending on the water content of the inclusions. Homogenization of the vapor bubble occurs from 850-1160°C, and complete melting of the silicate glass at about 950°C. The highly variable proportions of the individual phases in the silicate melt + salt + H2O inclusions and the coexistence of silicate melt + CO2 inclusions indicates immiscibility during the crystallization of the magma. Primary and secondary CO2 inclusions in the alkali syenite suite indicate lower densities (from 0.10 to 0.22 g/cm3) than those resulting from primary CO2 inclusions in the gabbroic suite (from 0.34 to 0.42 g/cm3). The P-T trajectory of the probable fluid evolution path shows that the crystallization of gabbro occurred between ∼1 and 1.4 kbars, whereas alkali syenite crystallized between ∼200 and 400 bars. The secondary H2O inclusions in alkali syenite were trapped in the later stages of the hydrothermal process and at much lower temperatures (130-290°C), but at pressures relatively close to those of alkali syenite crystallization. The almost isobaric conditions during the final stage of the fluid evolution path are explained by the very shallow emplacement of the alkali syenite intrusive body.",
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T1 - Fluid inclusion evidence for magmatic silicate/saline/CO2 immiscibility and geochemistry of alkaline xenoliths from Ventotene Island, Italy

AU - De Vivo, B.

AU - Török, K.

AU - Ayuso, R. A.

AU - Lima, A.

AU - Lirer, L.

PY - 1995

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N2 - Fluid and melt inclusions and geochemical features of alkali syenite, mafic, and ultramafic cumulate xenoliths in the last ignimbritic event (volcanism up to 300 ky.b.P.) at the island of Ventotene in the Pontine archipelago (Gaeta Gulf) were investigated to establish the genesis and evolution of the fluids trapped in the inclusions. Ranges in lead isotopic compositions of the xenoliths as a group are narrow: 206Pb/204Pb:18.778-18.864; 207Pb/204Pb:15.641-15.701; 208Pb/204Pb:38.858-39.090; the values overlap among the groups, implying that the xenoliths are closely related. The xenoliths straddle the best-fit line describing the regional NW-SE variation of values for uranogenic Pb in volcanic rocks from the Roman alkaline province. The similarity between the xenoliths and volcanic rocks permits the interpretation that the xenoliths are representative of the source region of the volcanic rocks, residues after partial melting of the source region or fractional crystallization of the volcanic rocks, or even that the xenoliths represent assimilants obtained during the evolution of the magmas that produced the volcanic rocks. Xenoliths belonging to the ultramafic-mafic cumulate group contain only silicate melt inclusions ± vapor bubble ± droplets of an opaque phase and rarely some CO2 trapped in silicate melt inclusions. Xenoliths in the alkali syenite group have three types of fluid inclusions: (1) single phase vapor and silicate melt inclusions; (2) two-phase silicate melt + salt, silicate melt + CO2 (V), aqueous (L + V), and silicate melt + vapor inclusions, and (3) three-phase and multiphase inclusions: CO2 (L) + CO2 (V) + H2O; silicate melt + saline melt + H2O ± birefringent or opaque trapped minerals; H2O + salt + silicate glass ± birefringent trapped minerals. During heating experiments, melting of salt occurs at temperatures from 565 to 815°C, depending on the water content of the inclusions. Homogenization of the vapor bubble occurs from 850-1160°C, and complete melting of the silicate glass at about 950°C. The highly variable proportions of the individual phases in the silicate melt + salt + H2O inclusions and the coexistence of silicate melt + CO2 inclusions indicates immiscibility during the crystallization of the magma. Primary and secondary CO2 inclusions in the alkali syenite suite indicate lower densities (from 0.10 to 0.22 g/cm3) than those resulting from primary CO2 inclusions in the gabbroic suite (from 0.34 to 0.42 g/cm3). The P-T trajectory of the probable fluid evolution path shows that the crystallization of gabbro occurred between ∼1 and 1.4 kbars, whereas alkali syenite crystallized between ∼200 and 400 bars. The secondary H2O inclusions in alkali syenite were trapped in the later stages of the hydrothermal process and at much lower temperatures (130-290°C), but at pressures relatively close to those of alkali syenite crystallization. The almost isobaric conditions during the final stage of the fluid evolution path are explained by the very shallow emplacement of the alkali syenite intrusive body.

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