Literature data on the non-linear dielectric behaviour of binary liquid mixtures have been recalculated with respect to the field dependence of the Kirkwood factor of the associating component. Thus the concentration-dependence of the first non-linear coefficient of the Kirkwood factor has been obtained. The dilution of the polar component by the apolar one alters the association equilibria, as is reflected in the first non-linear coefficient for both normal and anomalous dielectric saturation.
|Number of pages||8|
|Journal||Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases|
|Publication status||Published - Dec 1 1982|
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