Field-dependent Kirkwood factor in the non-linear dielectric behaviour of binary liquid mixtures

János Liszi, Erzsébet Papp, Imre Ruff

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Literature data on the non-linear dielectric behaviour of binary liquid mixtures have been recalculated with respect to the field dependence of the Kirkwood factor of the associating component. Thus the concentration-dependence of the first non-linear coefficient of the Kirkwood factor has been obtained. The dilution of the polar component by the apolar one alters the association equilibria, as is reflected in the first non-linear coefficient for both normal and anomalous dielectric saturation.

Original languageEnglish
Pages (from-to)915-922
Number of pages8
JournalJournal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
Volume78
Issue number3
DOIs
Publication statusPublished - Dec 1 1982

ASJC Scopus subject areas

  • Chemistry(all)

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