Ferrocenophanes with the bisphosphanotetryl bridge: Inorganic rings on the way to tetrylenes

Denis Kargin, Zsolt Kelemen, Kristijan Krekić, Martin Maurer, Clemens Bruhn, László Nyulászi, Rudolf Pietschnig

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

A series of [3]ferrocenophanes with functional P-E-P motifs (E = group 14 fragments) is reported. Out of these, the silicon compounds with the general formula Fe(C5H4PtBu)2SiXY (XY = Cl2, Br2, I2, H2, HCl) have been characterized by spectroscopic means and the bonding situation was analyzed using X-ray crystallography and quantum chemical calculations. Despite the two stereogenic phosphanyl centers, most of the [3]ferrocenophanes have been obtained as single isomers in the course of stereospecific reactions. The corresponding stannylene Fe(C5H4PtBu)2Sn has been obtained in the form of its dimeric adduct.

Original languageEnglish
Pages (from-to)2180-2189
Number of pages10
JournalDalton Transactions
Volume45
Issue number5
DOIs
Publication statusPublished - 2016

ASJC Scopus subject areas

  • Inorganic Chemistry

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    Kargin, D., Kelemen, Z., Krekić, K., Maurer, M., Bruhn, C., Nyulászi, L., & Pietschnig, R. (2016). Ferrocenophanes with the bisphosphanotetryl bridge: Inorganic rings on the way to tetrylenes. Dalton Transactions, 45(5), 2180-2189. https://doi.org/10.1039/c5dt03107a