Ferrihydrite precipitation in groundwater-fed river systems (Nete and Demer river basins, Belgium): Insights from a combined Fe-Zn-Sr-Nd-Pb-isotope study

V. M. Dekov, E. Vanlierde, K. Billström, C. D. Garbe-Schönberg, D. J. Weiss, G. Gatto Rotondo, K. Van Meel, E. Kuzmann, D. Fortin, L. Darchuk, R. Van Grieken

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

Two groundwater-fed river systems (Nete and Demer, Belgium) carry red suspended material that settles on the river bed forming red sediments. The local aquifer that feeds these river systems is a glauconite-rich sand, which provides most of the dissolved Fe to the rivers. The solid component of these systems, i.e., the red suspended material and sediments, has a simple mineralogy (predominantly ferrihydrite), but shows a complex geochemistry pointing out the different processes contributing to the river chemistry: (1) the red sediments have higher transition metal (excluding Cu) and detrital element (e.g., Si, Al, K, Rb, etc.) concentrations than the red suspended matter because of their longer residence time in the river and higher contribution of the background (aquifer) component, respectively; (2) the red suspended material and sediments have inherited their rare earth element (REE) patterns from the aquifer; (3) the origin of Sr present in the red suspended matter and red sediments is predominantly marine (i.e., Quaternary calcareous rocks), but a small amount is geogenic (i.e., from detrital rocks); (4) Pb in both solids originates mostly from anthropogenic and geogenic sources; (5) all of the anthropogenic Pb in the red suspended material and sediments is hosted by the ferrihydrite; (6) Nd budget of the red riverine samples is controlled by the geogenic source and shows little anthropogenic component; (7) the significant Fe- and Zn-isotope fractionations are in line with the previous studies. Their fractionation patterns do not correlate, suggesting that the processes controlling the isotope geochemistry of Fe and Zn are different: oxidation/reduction most likely governs the Fe-isotope fractionation, whereas adsorption/desorption or admixing of anthropogenic sources controls the isotope fractionation of Zn.

Original languageEnglish
Pages (from-to)1-15
Number of pages15
JournalChemical Geology
Volume386
DOIs
Publication statusPublished - Oct 29 2014

Fingerprint

ferrihydrite
Isotopes
Catchments
river system
Groundwater
Sediments
river basin
Rivers
isotope
Fractionation
groundwater
geogenic source
fractionation
Aquifers
sediment
Geochemistry
aquifer
anthropogenic source
geochemistry
Rocks

Keywords

  • Fe-Zn-Sr-Nd-Pb-isotopes
  • Ferrihydrite
  • Rivers
  • Sediments
  • Suspended matter

ASJC Scopus subject areas

  • Geochemistry and Petrology
  • Geology

Cite this

Dekov, V. M., Vanlierde, E., Billström, K., Garbe-Schönberg, C. D., Weiss, D. J., Gatto Rotondo, G., ... Van Grieken, R. (2014). Ferrihydrite precipitation in groundwater-fed river systems (Nete and Demer river basins, Belgium): Insights from a combined Fe-Zn-Sr-Nd-Pb-isotope study. Chemical Geology, 386, 1-15. https://doi.org/10.1016/j.chemgeo.2014.07.023

Ferrihydrite precipitation in groundwater-fed river systems (Nete and Demer river basins, Belgium) : Insights from a combined Fe-Zn-Sr-Nd-Pb-isotope study. / Dekov, V. M.; Vanlierde, E.; Billström, K.; Garbe-Schönberg, C. D.; Weiss, D. J.; Gatto Rotondo, G.; Van Meel, K.; Kuzmann, E.; Fortin, D.; Darchuk, L.; Van Grieken, R.

In: Chemical Geology, Vol. 386, 29.10.2014, p. 1-15.

Research output: Contribution to journalArticle

Dekov, VM, Vanlierde, E, Billström, K, Garbe-Schönberg, CD, Weiss, DJ, Gatto Rotondo, G, Van Meel, K, Kuzmann, E, Fortin, D, Darchuk, L & Van Grieken, R 2014, 'Ferrihydrite precipitation in groundwater-fed river systems (Nete and Demer river basins, Belgium): Insights from a combined Fe-Zn-Sr-Nd-Pb-isotope study', Chemical Geology, vol. 386, pp. 1-15. https://doi.org/10.1016/j.chemgeo.2014.07.023
Dekov, V. M. ; Vanlierde, E. ; Billström, K. ; Garbe-Schönberg, C. D. ; Weiss, D. J. ; Gatto Rotondo, G. ; Van Meel, K. ; Kuzmann, E. ; Fortin, D. ; Darchuk, L. ; Van Grieken, R. / Ferrihydrite precipitation in groundwater-fed river systems (Nete and Demer river basins, Belgium) : Insights from a combined Fe-Zn-Sr-Nd-Pb-isotope study. In: Chemical Geology. 2014 ; Vol. 386. pp. 1-15.
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abstract = "Two groundwater-fed river systems (Nete and Demer, Belgium) carry red suspended material that settles on the river bed forming red sediments. The local aquifer that feeds these river systems is a glauconite-rich sand, which provides most of the dissolved Fe to the rivers. The solid component of these systems, i.e., the red suspended material and sediments, has a simple mineralogy (predominantly ferrihydrite), but shows a complex geochemistry pointing out the different processes contributing to the river chemistry: (1) the red sediments have higher transition metal (excluding Cu) and detrital element (e.g., Si, Al, K, Rb, etc.) concentrations than the red suspended matter because of their longer residence time in the river and higher contribution of the background (aquifer) component, respectively; (2) the red suspended material and sediments have inherited their rare earth element (REE) patterns from the aquifer; (3) the origin of Sr present in the red suspended matter and red sediments is predominantly marine (i.e., Quaternary calcareous rocks), but a small amount is geogenic (i.e., from detrital rocks); (4) Pb in both solids originates mostly from anthropogenic and geogenic sources; (5) all of the anthropogenic Pb in the red suspended material and sediments is hosted by the ferrihydrite; (6) Nd budget of the red riverine samples is controlled by the geogenic source and shows little anthropogenic component; (7) the significant Fe- and Zn-isotope fractionations are in line with the previous studies. Their fractionation patterns do not correlate, suggesting that the processes controlling the isotope geochemistry of Fe and Zn are different: oxidation/reduction most likely governs the Fe-isotope fractionation, whereas adsorption/desorption or admixing of anthropogenic sources controls the isotope fractionation of Zn.",
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