Far-infrared study of C60-tetraphenylphosphoniumiodide

V. C. Long, J. L. Musfeldt, K. Kamarás, A. Schilder, W. Schütz

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

We report a far-infrared vibrational study of (Ph4P)2IC60 which reveals a room temperature Jahn-Teller distortion of the C60 monoanion to either a D5d or D3d reduced-symmetry point group. Temperature dependences of the intramolecular C60 and counterion vibrations indicate a weak phase transition of the bulk material occurring between 125 and 150 K.

Original languageEnglish
Pages (from-to)2435-2436
Number of pages2
JournalSynthetic Metals
Volume103
Issue number1-3
DOIs
Publication statusPublished - Jun 24 1999

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Infrared radiation
Point groups
Jahn-Teller effect
vibration
temperature dependence
Crystal symmetry
symmetry
room temperature
Phase transitions
Temperature

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Materials Chemistry
  • Polymers and Plastics

Cite this

Long, V. C., Musfeldt, J. L., Kamarás, K., Schilder, A., & Schütz, W. (1999). Far-infrared study of C60-tetraphenylphosphoniumiodide. Synthetic Metals, 103(1-3), 2435-2436. https://doi.org/10.1016/S0379-6779(98)00714-0

Far-infrared study of C60-tetraphenylphosphoniumiodide. / Long, V. C.; Musfeldt, J. L.; Kamarás, K.; Schilder, A.; Schütz, W.

In: Synthetic Metals, Vol. 103, No. 1-3, 24.06.1999, p. 2435-2436.

Research output: Contribution to journalArticle

Long, VC, Musfeldt, JL, Kamarás, K, Schilder, A & Schütz, W 1999, 'Far-infrared study of C60-tetraphenylphosphoniumiodide', Synthetic Metals, vol. 103, no. 1-3, pp. 2435-2436. https://doi.org/10.1016/S0379-6779(98)00714-0
Long, V. C. ; Musfeldt, J. L. ; Kamarás, K. ; Schilder, A. ; Schütz, W. / Far-infrared study of C60-tetraphenylphosphoniumiodide. In: Synthetic Metals. 1999 ; Vol. 103, No. 1-3. pp. 2435-2436.
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