Experimental determination of the inelastic mean free path (IMFP) of electrons in selected oxide films applying surface excitation correction

S. Gurban, G. Gergely, J. Toth, D. Varga, A. Jablonski, M. Menyhárd

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

The inelastic mean free path (IMFP) of electrons was determined using elastic peak electron spectroscopy (EPES) with Cu, Si, Ag, Ni and Au reference samples. Systematic differences occurred between the experimental and calculated (TPP-2M) (Tanuma, Powell, Penn) IMFPs, which can be ascribed partly to surface losses. The experimental IMFP was deduced from the integrated elastic peak ratio of the sample and the reference. Experiments were made with the ESA 31 (ATOMKI) and DESA 100 (Staib) electron spectrometers, and covered the E = 0.2-2 keV energy range. The results were evaluated applying Monte Carlo (MC) simulation based on the NIST SRD 64/3.1 database and using the EPESWIN software of Jablonski. The surface excitation correction (surface excitation parameter (SEP)) for SiO2, MgO and Al2O3 was determined using our new procedure applying the model of Chen and Tanuma. This correction reduced the difference between uncorrected, experimentally determined and calculated IMFPs by nearly 50%, which proves the importance of the contribution of surface excitation. The oxide layers studied are insulators. Their surface potential was determined by the energy of the Auger peak. We observed an energy shift of 1-3 eV of the Auger peak positions due to charging. The SEP material parameter resulted in ach = 1.2 for SiO2 and a ch = 4 for MgO and Al2O3.

Original languageEnglish
Pages (from-to)624-627
Number of pages4
JournalSurface and Interface Analysis
Volume38
Issue number4
DOIs
Publication statusPublished - Apr 2006

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mean free path
Oxide films
oxide films
Electrons
excitation
electrons
Electron spectroscopy
Surface potential
Oxides
Spectrometers
European Space Agency
electron spectroscopy
charging
energy
insulators
spectrometers
computer programs
oxides
shift
Experiments

Keywords

  • IMFP
  • Insulators
  • Surface correction

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Colloid and Surface Chemistry

Cite this

Experimental determination of the inelastic mean free path (IMFP) of electrons in selected oxide films applying surface excitation correction. / Gurban, S.; Gergely, G.; Toth, J.; Varga, D.; Jablonski, A.; Menyhárd, M.

In: Surface and Interface Analysis, Vol. 38, No. 4, 04.2006, p. 624-627.

Research output: Contribution to journalArticle

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