Expanding the scope of metal-free catalytic hydrogenation through frustrated Lewis pair design

Research output: Contribution to journalArticle

169 Citations (Scopus)

Abstract

No metal causes frustration: Based on a conceptual framework, novel frustrated Lewis acid-base catalyst systems with orthogonal reactivity have been developed. Aside from enhanced functional-group tolerance, unique chemoselectivity can be achieved in catalytic metal-free hydrogenations (see scheme).

Original languageEnglish
Pages (from-to)6559-6563
Number of pages5
JournalAngewandte Chemie - International Edition
Volume49
Issue number37
DOIs
Publication statusPublished - Sep 3 2010

Fingerprint

Hydrogenation
Metals
Lewis Acids
Functional groups
Catalysts
Acids

Keywords

  • Amines
  • Boranes
  • Catalytic hydrogenation
  • Frustrated Lewis pairs
  • Hydrogen activation

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis

Cite this

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title = "Expanding the scope of metal-free catalytic hydrogenation through frustrated Lewis pair design",
abstract = "No metal causes frustration: Based on a conceptual framework, novel frustrated Lewis acid-base catalyst systems with orthogonal reactivity have been developed. Aside from enhanced functional-group tolerance, unique chemoselectivity can be achieved in catalytic metal-free hydrogenations (see scheme).",
keywords = "Amines, Boranes, Catalytic hydrogenation, Frustrated Lewis pairs, Hydrogen activation",
author = "G{\'a}bor Eros and H. Mehdi and I. P{\'a}pai and T. Rokob and P. Kir{\'a}ly and G. T{\'a}rk{\'a}nyi and T. So{\'o}s",
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T1 - Expanding the scope of metal-free catalytic hydrogenation through frustrated Lewis pair design

AU - Eros, Gábor

AU - Mehdi, H.

AU - Pápai, I.

AU - Rokob, T.

AU - Király, P.

AU - Tárkányi, G.

AU - Soós, T.

PY - 2010/9/3

Y1 - 2010/9/3

N2 - No metal causes frustration: Based on a conceptual framework, novel frustrated Lewis acid-base catalyst systems with orthogonal reactivity have been developed. Aside from enhanced functional-group tolerance, unique chemoselectivity can be achieved in catalytic metal-free hydrogenations (see scheme).

AB - No metal causes frustration: Based on a conceptual framework, novel frustrated Lewis acid-base catalyst systems with orthogonal reactivity have been developed. Aside from enhanced functional-group tolerance, unique chemoselectivity can be achieved in catalytic metal-free hydrogenations (see scheme).

KW - Amines

KW - Boranes

KW - Catalytic hydrogenation

KW - Frustrated Lewis pairs

KW - Hydrogen activation

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