Exciplex laser photolysis study of acetone with relevance to tropospheric chemistry

Rebeka Nádasdi, Gergely Kovács, István Szilágyi, Attila Demeter, Sándor Dóbé, Tibor Bérces, Ferenc Márta

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20 Citations (Scopus)

Abstract

Exciplex laser photolysis at 248 and 308 nm wavelengths coupled with gas-chromatographic analysis was applied to determine the photodissociation quantum yield of acetone (QY). At 308 nm, QY has been found to decrease with decreasing temperature (T = 323-233 K) and to decrease with increasing pressure (P = 13-998 mbar synthetic air) supporting the recent suggestion that the photolysis of acetone plays a less important role in the chemistry of the upper troposphere than previously thought. Water vapour has no effect on QY in disagreement with a recent publication.

Original languageEnglish
Pages (from-to)31-35
Number of pages5
JournalChemical Physics Letters
Volume440
Issue number1-3
DOIs
Publication statusPublished - May 25 2007

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ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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