Über die Austauschreaktionen der Zentralatome in Lanthanid-Aminopolycarbonsäure-Komplexen, III. Mitt. Kinetische Untersuchungen der Isotopen-Austauschreaktionen von Tb3+-Ionen mit Tb EDTA-, Tb HEDTA-bzw. Tb DCTA-Komplexen

Translated title of the contribution: Exchange reactions of the central atoms in lanthanide-aminopolycarboxylate complexes, III: Kinetical investigation of isotopic exchange reactions of Tb3+ ions with TbEDTA, TbHEDTA, and TbDCTA complexes, resp

P. Szarvas, E. Brücher

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2 Citations (Scopus)

Abstract

The kinetics of isotopic exchange reactions between Tb3+-ions and Tb EDTA, Tb HEDTA as well as Tb DCTA-complexes, at pH-s between 2,98 and 6,8 has been investigated. On the basis of the determinated rate equations, the possibilities of the exchange mechanisms are in detail discussed and some conclusions about the bonding-and structural-problems of the Tb-APK-complexes are obtained.

Original languageGerman
Pages (from-to)1321-1329
Number of pages9
JournalMonatshefte für Chemie
Volume101
Issue number5
DOIs
Publication statusPublished - Sep 1 1970

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ASJC Scopus subject areas

  • Chemistry(all)

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